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Far-infrared spectroscopy of dimethyl-ether and its 13 C-enriched isotopologues and first spectroscopic characterization of tert-butyl-dibromophosphane / Pia Kutzer

データ種別 電子ブック
出版情報 Kassel : Kassel University Press , [2016]
本文言語 英語
大きさ 1 online resource (xiv, 127 pages)

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大阪芸大図書館
URL (芸大)電子ブック 電子ブック（EBSCO: eBook Open Access Collection）
EB2202507
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9783737602259

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資料種別 機械可読データファイル
内容注記 Front Cover; Titelseite; Impressum; Widmung; Abstract; Zusammenfassung; Contents; List of Figures; List of Tables; 1. Preposition; 2. Theoretical Considerations; 2.1. Rotational Spectroscopy; 2.1.1. Rotational Energy; 2.1.2. Symmetric Top Molecules; 2....1.3. Asymmetric Top Molecules; 2.1.4. Spectral Line-shapes and Intensities; 2.2. Vibrational Spectroscopy; 2.2.1. General Considerations; 2.2.2. Normal Modes of Polyatomic Molecules; 2.2.3. Rotation-Vibration Coupling; 3. Far-infrared Spectra of Dimethyl-Ether Isotopologues; 3.1. Introduction; 3.2. Theoretical Treatment of DME
3.2.1. Molecular Symmetry3.2.2. Internal Motions; 3.2.3. Selection Rules and Spin Statistical Weights for Rotational Transitions; 3.3. Experimental Setup; 3.3.1. Chemical Preparation of Pure 13C Substituted DME; 3.3.2. Fourier Transform Infrared Spectrometer; 3.3.3. Bruker IFS 125 HR Spectrometer at the AILES Beamline; 3.4. Spectra and Analysis; 3.4.1. Measurements of DME; 3.4.2. Data Reduction and Fitting Procedure; 3.4.3. Experimental Results; 3.5. Summary and Conclusion; 4. Spectroscopical Characterization of Tert-butyl-dibromophosphane; 4.1. Introduction; 4.2. Ab initio Calculations
4.3. Experimental Setup for tBuPBr24.3.1. Chemical Synthesis of tBuPBr2; 4.3.2. IR-FT Spectroscopic Investigation; 4.3.3. SOLEIL Laboratories; 4.3.4. Kassel Laboratories; 4.4. Spectra and Analysis of tBuPBr2; 4.4.1. Measurements of tBuPBr2; 4.4.2. Fitting Procedure; 4.4.3. Experimental Results; 4.5. Results and Conclusions; 5. Conclusion and Outlook; Appendix; A. Useful Tables; B. Bibliography; Danksagung; Parts of this work have been published; Oral contributions at international conferences; Funding Acknowledgements; Back Cover  続きを読む
一般注記 In English with abstract in German
Open Access
Includes bibliographical references (pages 121-128)
Vendor-supplied metadata
著者標目 *Kutzer, Pia,
件　名 LCSH:Methyl ether
LCSH:Infrared spectroscopy
LCSH:Vibration -- Testing  全ての件名で検索
BISACSH:SCIENCE -- Chemistry -- Analytic  全ての件名で検索
FREE:Infrared spectroscopy
FREE:Methyl ether
FREE:Vibration -- Testing...  全ての件名で検索
LCSH:Electronic books
BSH:Electronic books   続きを読む
分　類 DC23:543.08583
書誌ID ED00003690
ISBN 9783737602259

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